Bleaching of Groundnut Oil Using Activated Rice Husk: A Suitable Alternative to Commercial Adsorbents
Published: 2023-12-29
Page: 941-952
Issue: 2023 - Volume 6 [Issue 4]
Dallacoasta Iyayosa Andrea *
Department of Chemical Engineering, Federal University of Technology, Minna, P.M.B. 65, Niger State, Nigeria.
Abdullahi Abdulsalam
Department of Environmental Health and Safety, Maryam Abacha American University of Niger, Niger.
Habibu Uthman
Department of Chemical Engineering, Federal University of Technology, Minna, P.M.B. 65, Niger State, Nigeria.
Oluwatosin Sarafa Azeez
Department of Chemical Engineering, Federal University of Technology, Minna, P.M.B. 65, Niger State, Nigeria.
*Author to whom correspondence should be addressed.
Abstract
Absorbent bleaching of crude groundnut oil was performed using activated rice husk as an adsorbent. The study focused on refining the oil by eliminating unwanted components. Response surface methodology was employed to optimize the bleaching process by analyzing the impact of time, adsorbent dosage, particle size, and temperature. Interactive effects on absorbance and peroxide value were also investigated. Bleaching efficiency was determined by measuring absorbance, with a 46.78% reduction observed (from 0.962 to 0.512). The peroxide value decreased from 13.333 to 3.571 mEq/kg of oil. Physiochemical properties were within the acceptable codex brought range. Fourier-transform infrared spectroscopy revealed decreased impurity concentrations, such as nitrile functional groups and unsaturated fatty acids. In conclusion, bleaching positively affected the oil's physiochemical properties, and rice husk proved to be a suitable alternative to commercial adsorbents.
Keywords: Bleaching, groundnut oil, rice husk, optimization, peroxide value, RSM
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References
Gunstone FD. Vegetable oils in food Technology: Composition, Properties and Uses, Second Edition; 2011. DOI: 10.1002/9781444339925.
Alhassan M, Auta M, Sabo J, Umaru M, Kovo A. CO2 Capture Using Amine-impregnated activated carbon from jatropha curcas Shell, Br J Appl Sci Technol. 2016;14(4). DOI: 10.9734/bjast/2016/24253.
Abdulsalam A, Yaro NA, Alhassan B, Ibrahim YS, Andrea DI, Olanrewaju OA, Lawal K. Emerging contaminants removal from wastewater using organo-modified bentonite clay, Journal of Engineering Research and Reports. 2023;25(10):121–144. DOI: 10.9734/jerr/2023/v25i101006.
Abdulsalam A, Yaro NA, Mohammed A, Ibrahim YS, Yakasai KM, Andrea DI. Kinetic studies of emerging contaminants removal from wastewater using organo modified activated carbon. International Journal of Innovative Science and Research Technology. 2023;8(10). Available: www.ijisrt.com
AOAC, Association of official analytical chemists, Chemical and Functional Properties of Food Saccharides. 1990;1(1).
Abdullahi A, Alhassan M, Isah AG, Sani KA, Olalekan OA. Comparative studies on the kinetics of biogas purification using activated Carbon and Zeolite, in IOP Conference Series: Earth and Environmental Science; 2018. DOI: 10.1088/1755-1315/173/1/012046.
Alimentarius C. Codex standard for named vegetable oils CX-STAN 210- 1999, Codex Standard. 2001;8.
Foletto EL, Paz DS, Gündel A. Acid-activation assisted by microwave of a brazilian bentonite and its activity in the bleaching of soybean oil, Appl Clay Sci. 2013:83–84. DOI: 10.1016/j.clay.2013.08.017.
Jung MY, Yoon SH, Min DB. Effects of processing steps on the contents of minor compounds and oxidation of soybean oil, J Am Oil Chem Soc. 1989;66(1). DOI: 10.1007/BF02661798.
Rossi M, Gianazza M, Alamprese C, Stanga F. The role of bleaching clays and synthetic silica in palm oil physical refining, Food Chem. 2003;82(2). DOI: 10.1016/S0308-8146(02)00551-4.
Birch G. Pearson’s composition and analysis of foods 9th edn By R. S. Kirk and R. Sawyer. Longman, UK, 1991. x + 708 pp. ISBN 0-582-409101. Price: £49.00, Food Chem. 1993;46:1. DOI: 10.1016/0308-8146(93)90087-v.
Oderinde RA, Ajayi IA, Adewuyi A. Characterization of seed and seed oil of Hura crepitans and the kinetics of degradation of the oil during heating, Electronic Journal of Environmental, Agricultural and Food Chemistry. 2009;8(3).
Harold Egan, Ronald S. Kirk, Ronald Sawyer, Rev. ed. of: Pearson's chemical analysis of foods”, 8th ed. Harlow, Essex, U.K.: Longman; New York, NY: Wiley; 1981.
Verma PC. To study the effect of bleaching on some parameters of groundnut oil and its applications in industrial field; 2016.
NIST. NIST/EPA/NIH Mass Spectral Library (NIST 14) and NIST Mass Spectral Search Program (Version 2.2), The National Institute of Standards and Technology NIST. Gaithersburg, MD, US.; 2014.